Nobody knows the remarkable properties of human skin like the researchers struggling to emulate it. Not only is our skin sensitive, sending the brain precise information about pressure and temperature, but it also heals efficiently to preserve a protective barrier against the world.
Combining these two features in a single synthetic material presented an exciting challenge for researchers led by Bao.
Now, they have succeeded in making the first material that can both sense subtle pressure and heal itself when torn or cut. In the last decade, there have been major advances in synthetic skin, said Bao, but even the most effective self-healing materials had major drawbacks. Some had to be exposed to high temperatures, making them impractical for day-to-day use. Others could heal at room temperature, but repairing a cut changed their mechanical or chemical structure, so they could only heal themselves once. Most importantly, no self-healing material was a good bulk conductor of electricity, a crucial property.
"To interface this kind of material with the digital world, ideally you want them to be conductive," said Benjamin Chee-Keong Tee. The researchers succeeded by combining two ingredients to get what Bao calls "the best of both worlds" – the self-healing ability of a plastic polymer and the conductivity of a metal. They started with a plastic consisting of long chains of molecules joined by hydrogen bonds – the relatively weak attractions between the positively charged region of one atom and the negatively charged region of the next. "These dynamic bonds allow the material to self-heal," said Chao Wang. The molecules easily break apart, but then when they reconnect, the bonds reorganize themselves and restore the structure of the material after it gets damaged, he said. The result is a bendable material, which even at room temperature feels a bit like saltwater taffy left in the fridge.
To this resilient polymer, the researchers added tiny particles of nickel, which increased its mechanical strength. The nanoscale surfaces of the nickel particles are rough, which proved important in making the material conductive. Tee compared these surface features to "mini-machetes," with each jutting edge concentrating an electrical field and making it easier for current to flow from one particle to the next.
The result was a polymer with uncommon characteristics. "Most plastics are good insulators, but this is an excellent conductor," Bao said. The next step was to see how well the material could restore both its mechanical strength and its electrical conductivity after damage. The researchers took a thin strip of the material and cut it in half with a scalpel. After gently pressing the pieces together for a few seconds, they found the material gained back 75 percent of its original strength and electrical conductivity. The material was restored close to 100 percent in about 30 minutes. The same sample could be cut repeatedly in the same place. After 50 cuts and repairs, a sample withstood bending and stretching just like the original.
The composite nature of the material created a new engineering challenge for the team. Bao and her colleagues found that although nickel was key to making the material strong and conductive, it also got in the way of the healing process, preventing the hydrogen bonds from reconnecting as well as they should. For future generations of the material, Bao said the team might adjust the size and shape of the nanoparticles, or even the chemical properties of the polymer, to get around this trade-off.
The team also explored how to use the material as a sensor. For the electrons that make up an electrical current, trying to pass through this material is like trying to cross a stream by hopping from stone to stone. The stones in this analogy are the nickel particles, and the distance separating them determines how much energy an electron will need to free itself from one stone and move to another.
MEDICA.de; Source: Stanford School of Engineering